The presence of IRON in groundwater has several origins ; in the form of pyrites ( FeS2 ) , it is usually associated with sedimentary rocks deposited in a reducing environment ( marls, clays ) and metamorphic rocks.
It is usually found in strong concentrations in the water of weathered bedrock.
The following concentrations in groundwater are reported by ACF :
Sedimentary ( Cambodia , 1998 ) : 3-15 mg / l.
Bedrock ( Uganda , 1996 ) : 0,5 - 1,5 mg / l.
When present in reduced ( ferrous ) form ( Fe2+ or Fe ( II ), iron is oxidised by atmospheric oxygen and precipitates in oxidised ( ferric ) form ( Fe3+ or Fe ( III ), when water is pumped.
This produces rust stains on the slabs of boreholes or wells, and users may not find the water acceptable, because it stains laundry and has a pronounced taste when consumed directly or in hot drinks.
Treatment to remove iron involves aeration of the water in order to oxidise the dissolved Fe2+ to Fe3+, which then precipitates and can be removed by filtration.
In-situ analysis is recommended.
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AEP standard upper limit is 0,2 mg / l.
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WHO recommendation : < 0,3 mg/l.

